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Showing posts with label emerald. Show all posts
Showing posts with label emerald. Show all posts

Wednesday, June 27, 2012

Finding Gemstone Deposits:

Ruby crystal on calcite
photo by Rob Lavinsky

Gems have been prized for thousands of years, for their color, luster, durability, hardness and their high intrinsic value per volume.  They are found in all kinds of geologic environments of all ages from thousands of million years to recent times.  Gemstones are also found in all kinds of rocks ranging from igneous to metamorphic to sedimentary and are classified according to the environment where they were formed.  The deposits are rare because of the geological conditions needed to form them are exceptional.  For example, in order for the Emerald to form the beryllium from which it is made has to come in contact with chromium or vanadium.  These elements travel in entirely different geochemical circles that are the exception rather than the rule.

It is important to realize that like any other commodity, gems are subject to the laws of supply and demand.  Even though the demand for gems remains about the same the supplies are becoming depleted.  Many of the gems especially the colored variety are mined in Third World countries by artesianal methods, i.e. by hand.  In any of these countries the discovery of the new deposit often leads to a local prosperity, but many of these stones become involved in the illegal trade that is being used to finance terrorism.

Sapphire crystal
Photo by Rob Lavinsky



These deposits of gemstones are volcanic in origin and are formed deep within the Earth’s crust.  Gemstones from this origin have formed over 100 Km below the surface and are brought to the surface as the result of magma intrusions or lava flows.  Diamonds are one type of this deposit that has formed from 100 to 150 Km below the surface.  These gemstones are found in potassium rich stone called “kimberlite” that is brought to the surface in an explosive eruption that proceeds at near supersonic speeds.  There seems to be a rule known as Clifford's rule that these eruptions take place in Achaean terranes or come up through younger terranes overlying Achaean terrenes.  Kimberlite is quite rich in peridot and appears to be full of xenoliths that are torn off the walls of the magma channel.  A cross-sectional view of the kimberlite is like looking at a carrot.  The stone itself is quite soft and easily eroded away with the diamonds being carried away with the rest of the erosion products.

Diamonds are not the only product that is found in a magmatic deposit so are others stones such as sapphires and zircons.  Sapphires are also formed under some very specific geological conditions the most important one is a magmatic stone that is low in primary silicates such as basalt.  The sapphires form as crystals in the basalt and they're released as products of erosion.  Although they form in the basalt they are rarely mined directly.  Zircons are another example of a gemstone that is found in a magmatic deposit.  Once again these gemstones are not mined directly from the stone that are found as the products of erosion.  In geology zircons are thought to be forever and the oldest dated minerals in the world are some zircons that were found in Western Australia that were dated at 4.5 billion years old.  Zircons are used by geochemists worldwide for dating formations of different ages, and are highly effective in this use.

Some other gemstone minerals that are found in magmatic deposits include:
Peridot, gem quality olivine usually found in mantle xenoliths.
Labradorite, found as gem quality grains in some basalts.
Zircon, found as crystals in granite, basalt and the rarer carbonatites.
Apatite, found as crystals in carbonatites.
Garnets, found as crystals in basalts as xenocrysts and granite.

Emerald crystal on calcite
Photo by Eva Krocher



Pegmatites are hydrothermal deposits contain more different types of gemstones in any other rock.  These are formed from the volatile rich fluids that are found in pegmatites when they are formed.  In some geological circles pegmatites are called “Giant granite” because they have the same minerals as granite except the crystals of the individual minerals are much larger.  There are two different kinds of pegmatites simple and complex; most of the valuable minerals are found in complex pegmatites.  Although many of these minerals could be classified as gems other minerals found in pegmatites are the ores for rare metals such as niobium or rare earths. 

Depending on the fluids present when the pegmatite is solidifying different gemstones are deposited.  If the fluid is rich in fluorine topaz will be deposited.  A beryllium rich fluid will produce the mineral beryl in its many forms ranging from aquamarine, emerald, morganite, or heliodor.  Lithium rich fluid is another possibility depositing spodumene or other lithium rich minerals.  Pollucite is deposited from a cesium rich fluid.  In some cases the fluid is rich in several different elements producing “Tourmaline” a gemstone that is actually rarer them diamonds.  A manganese rich fluid will cause spessertine garnet to be deposited.

There are specific zones in a pegmatite where gemstones are found.  Many of them are found in cavities called “Vugs.”  The crystals formed in this environment are usually clear and well formed.  A deposit of this nature containing red and green tourmaline was discovered in the 1970s at Newry, Maine that was worth more then $8 million from a single vug as large as a bedroom.

There are other hydrothermal environments that are also capable of producing gemstones ranging from volcanic rocks to sedimentary rocks.  This is where one is likely to encounter agates, petrified wood, opal, amethyst as well as a whole plethora of gems.  Turquoise is another mineral deposited by hydrothermal waters.  It is copper phosphate and its beautiful sky blue botryoidal masses have been admired for over two thousand years.

Metamorphic deposits:


Diamond crystal in matrix - USGS


The only gem minerals normally found in metamorphic rocks are garnet, zoisite (variety tanzanite), rubies and emeralds.  Rubies are the red variety of the mineral corundum that is aluminum oxide.  These gems are found in cordierite rich gneiss as well as marble.  Sometimes rubies are carried up from the depths of the earth as xenocrysts in basalt.  Most of the world's emeralds are found in low grade carbonaceous schist in ColombiaOther gemstones that occur in metamorphic rocks are iolite (the gem-quality lilac-purple variety of cordierite), titanite and kyanite.
Jade is another mineral that is found in high-pressure; low-pressure blue schist metamorphic rocks.  There are two entirely different minerals that are recognized as jade in the trade one of these as jadeite a compact variety of the mineral pyroxene, and the other is nephrite a compact variety of the mineral that is derived from tremolite.  Although these minerals are composed of common minerals it takes a very special environment for them to form.


Sedimentary deposits:


By far the most valuable gemstone found in sedimentary rock is precious opal.  The largest deposits of this mineral in the world are found in central Australia.  Other deposits are found in the United States and Mexico.  Most opal is found as a replacement for fossils.  Opal also occurs as replacement beds or blebs in sedimentary rock.  A good piece of opal showing good colors can be as expensive as a diamond.


Placer deposits:


In some placer deposits gemstones are relatively abundant particularly in areas where the local rocks are known to produce gemstones.  This is especially true in areas underlying by cordierite gneiss or marble.  Another area is where gemstone bearing pegmatites are abundant.  Because of their toughness and hardness gemstones that are eroded from their country rock tend to remain intact preserving the best gemstones.  The same rough and tough treatment these stones go under as a result of natural processes particularly running water the weaker and softer stones are broken up leaving behind the highest quality gemstones.  Most of the gemstones in the world are recovered from placer deposits.  In some cases the work of recovery can be quite primitive; in others the most modern technology and machinery is used.


References:


Mineralogical Association of Canada, Editor Lee A. Groat, Geology Of Gem Deposits, Short Course Series, Volume 37, Yukon Geological Survey, © 2007, Yellowknife, Northwest Territories
Gem Deposits, http://amonline.net.au/geoscience/earth/gem.htm
Geology of Gem Deposits, Mineralogical Association of Canada, Editor Lee A. Groat, http://www.mineralogicalassociation.ca/doc/promo_SC37.pdf  Volume 37 © 2007

Thursday, March 8, 2012

Beryl the Genstone of Many Colors


Beryl crystals from Pakistan var. aquamarine
Photo by Gia Cassa


As a mineral beryl is beryllium aluminum cyclosilicate possessing the chemical formula Be3Al2(SiO3)6­.   As a gem it comes in many colors although pure beryl is colorless of the variety goshenite named after the town of Goshen in the central Berkshires of Massachusetts its type locality.  It is tinted by different colors causing it to be colored blue, green, red, yellow and white.  This is a mineral that is usually found in pegmatites although it is often found in biotite schists and in intruded limestone.  A rare occurrence is found in Utah called bixbite that has been colored red by manganese as an impurity.  Other gems in this family include aquamarine, emerald, green beryl, heliodor and morganite

An emerald crystal from Colombia
Photo by Gery Parent


Aquamarine is the color of sea water a bluish green with green beryl as a sub-order of aquamarine.  Emerald of course is bright green that is usually found in heavily intruded limestone although some occurrences are in biotite schist.  Heliodor is the yellow variety of beryl that is sometimes galled “golden beryl.”  Morganite is sometimes found associated with both aquamarine and golden beryl, bit is differentiated by its pink color.  Red beryl is also called bixbite or red emerald because of its red coloration.  Of all the beryl’s bixbite is the rarest, but only occurs in small crystals allowing gems cut from it to be lass then 5 carets in weight,

Golden beryl or heliodor
unknown


Beryl aside from its use as a gem is also the ore of beryllium where it occurs in granitic pegmatites.  One such crystal was a giant that occurred in the Bumpus Quarry in Albany, Maine that was about 5.5 meters long by 1.2 meters in diameter that weighed around 18 metric tons.  The largest crystal of any kind of mineral was found in Madagascar is a beryl crystal that was 18 meters long by 3.5 meters in diameter.  That is the size as the boiler on a steam locomotive.

A crystal of red beryl var. bixbite from Utah
Photo by Rob Lavinsky


Beryl is found on all the continents wherever crystalline igneous or metamorphic rocks are found.  The gems are found in the core of pegmatites where at times terminated crystals are found growing into cavities or vugs in the rock.  Some beryl like the emeralds found in Columbia are found in a peculiar black limestone that has been intruded with granite that contain in addition to the beryl an abundant amount of pyrite that certainly predates the formation of the emerald crystals.. Beryl is also found associated with biotite schist.   Many of the emeralds found in the Ural Mountains of Russia are this type of deposit.  The emeralds found at the Crabtree Corners deposit in North Carolina are also an example of this kind of deposit.

A crystal of morganite on albite and quartz.
Photo by Rob Lavinsky


One of the most important deposits of aquamarine in the United States is found in the Maryall district of New Milford, Connecticut where they occur in a large pegmatite that that was originally mined for feldspar and mica.  This mine has produced some fine specimens of both aquamarine and heliodor beryl including a 44 carat heart on display in the American Museum of Natural History in New York City.  It is also known to produce many other minerals especially large garnets and uranium minerals.  

Monday, February 20, 2012

Aquamarine as a Gemstone


Aquamarine is a member of the beryl family of gemstones that is usually colored various shades of blue/green or may appear as either light green or even as dark blue stones rivaling sapphire in color.  The mineral is a beryllium aluminum cyclosilicate with the formula Be3Al2(SiO3)6Terminated crystals of beryl are relatively rare, but are known to occur.  The stone has a value as a gemstone, and is a common ore of the metal beryllium.  In the case of aquamarine a small amount of iron that causes crystal defects in the crystal is the cause of its color.  The mineral beryl because of impurities in the crystal does occur in several different colors including green blue, yellow, red and white.

Aquamarine in a matrix of feldspar crystals.and other minerals including schorl the black crystal in the middle of the specimen.
Photo by Rob Lavinsky


The colors of aquamarine can range from light blue like that of the sky to a deep blue of the sea.  The darker the color the higher the price some aquamarines can sell for as much as $2,000 per caret although lighter stones only fetch a few dollars per carat.  The stone itself is fascinatingly beautiful with much appeal to women all over the world because it can complement or eye color.  For creative gemstone cutters it is an inspiration because of its ability to be cut in so many designs and still keep its beauty.

A water etched crystal of aquamarine from Brazil
Photo by Rob Lavinsky

Aquamarine is epitomized by its blue color, and the deeper blue the color the more expensive the stone making it one of the most popular stones rivaling at times its more expensive cousin emerald that also belongs to the beryl family.  The stone is hard enough at Mohs hardness of 7.5 to 8 so it can be used in most types of jewelry making it almost as popular as the classic stones emerald, ruby and sapphire.  In reality aquamarine is related to the emerald, but unlike its more famous cousin it usually free of flaws.  One flaw that is sometimes seen in aquamarine is long thin tubes that sometimes lend to its beauty in the form of chatoyancy forming tiger eyes or more rarely a star stone much like star sapphire.  Both forms of the stone command very high prices.

An example of a pear shaped aquamarine faceted gem.
Photographer Unknown


The color of aquamarine is caused by ions of iron causing crystal defects in the mineral beryl that is normally clear that is called goshenite my mineralogists because its type locality is in Goshen, Massachusetts were it is found in lithium bearing pegmatites.  Aquamarine can range from a pale blue to a strongly colored sea blue.  In some aquamarines you can see a light greenish simmer that is a typical feature of the stone.  Thee most prized color however is a pure clear blue transparent stone bringing out the transparency and shine of this magnificent stone.